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We construct finite $$R$$-matrices for the first fundamental representation $$V$$ of two-parameter quantum groups $$U_{r,s}(\mathfrak{g})$$ for classical $$\mathfrak{g}$$, both through the decomposition of $$V\otimes V$$ into irreducibles $$U_{r,s}(\mathfrak{g})$$-submodules as well as by evaluating the universal $$R$$-matrix. The latter is crucially based on the construction of dual PBW-type bases of $$U^{\pm}_{r,s}(\mathfrak{g})$$ consisting of the ordered products of quantum root vectors defined via $(r,s)$-bracketings and combinatorics of standard Lyndon words. We further derive explicit formulas for affine $$R$$-matrices, both through the Yang-Baxterization technique of [Internat. J. Modern Phys. A 6 (1991), 3735-3779] and as the unique intertwiner between the tensor product of $V(u)$ and $V(v)$, viewed as modules over two-parameter quantum affine algebras $$U_{r,s}(\widehat{\mathfrak{g}})$$ for classical $$\mathfrak{g}$$. The latter generalizes the formulas of [Comm. Math. Phys. 102 (1986), 537-547] for one-parametric quantum affine algebras.